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杨高升


     
       
 

杨高升  教授、博士生导师

   邮箱: gshyang@ahnu.edu.cn          电话:  13955391536

   实验室: 1007-1008 (礼勤楼)            办公室: 1119 (礼勤楼)

   ORCID:  http://orcid.org/0000-0002-7891-3972

 

所受教育

1981年9月–1985年7月  维多利亚3308老品牌化学系学习,获学士学位 

1988年9月–1991年7月  维多利亚3308老品牌有机化学研究所硕士研究生,获理学硕士学位

2002年9月–2005年6月  南京大学化学化工学院博士研究生,获理学博士学位 

 职称职位 

1985年7月–现在  维多利亚3308老品牌助教,讲师,副教授,教授 (2005年) 

2004年6月–现在  维多利亚3308老品牌硕士生导师 

2012年7月–现在  维多利亚3308老品牌博士生导师 

 主持项目

1. “稀土有机化合物催化不饱和键对氮氢键的不对称串联插入反应”,国家自然科学基金面上项目,直接经费65万元,2017年1月–2020年12月,项目负责人 (21672005)

2. “多取代D–A型环丙烷与芳香醛的[3+2]环加成反应及其在呋喃木酚素合成中的应用”,国家自然科学基金面上项目,60万元,2012年1月–2015年12月,项目负责人 (21172002) 

3. “新型二胺稀土配合物的合成及其催化烯烃氢胺化反应研究”,国家自然科学基金面上项目,37万元,2010年1月–2012年12月,项目负责人 (20972001) 

4. “手性胺–硫脲催化的不对称多组分反应研究”,安徽省自然科学基金面上项目,5万元,2009年1月–2011年12月,项目负责人 (090416236) 

 研究领域

1. 金属有机化学 

2. 有机合成化学 

3. 不对称催化 

 讲授课程

1. 有机化学-I(本科)

2. 有机化学-II(本科)

3. 有机波谱分析(本科)

4. 有机合成化学(本科)

5. 有机波谱学(硕士)

 获奖情况

1. 安徽省“教学名师”(2015年)

2. 维多利亚3308老品牌“教学名师”(2013年)

3. 维多利亚3308老品牌优秀教学奖特等奖 (2011年)

4. 维多利亚3308老品牌“三育人”先进工作者 (2007年)

5. 维多利亚3308老品牌“皖泰”教师教学优秀奖一等奖 (2001年)

 研究进展

                                                                                                                         


                                                                                                                           

 

1AE4E

1FC52

 

  代表性论文

34. Dongcheng Zheng, Rui Zhang, Wenlong Chen, Pengfei Yang, Gaosheng Yang* and Zhuo Chai, “Lewis Acid-Catalyzed Annulations of geminally-Disubstituted Cyclopropanes with Aldehydes or 1,3,5-Triazinanes”, Org. Lett. 2023, 25, 2577–2581. 

33. Wenlong Chen, Huimin Li, Pengfei Yang, Dongcheng Zheng, Gaosheng Yang*, “Reaction of 2-Aroylmethylenemalonates with Corey Ylide”, Chin. J. Org. Chem. 2023, 43, 1472–1482. (陈文龙, 李慧敏, 杨鹏飞, 郑东程, 杨高升*, “2-芳甲酰基甲亚基丙二酸酯与Corey叶立德的反应”, 有机化学, 2023, 43, 1472–1482.) 

32. Jinsong Hou, Gaosheng Yang*, “Reaction of Tandem Addition of Aliphatic Amines to Alkenylnitriles Catalyzed by Tris(o-dimethylaminobenzyl)yttrium”, Chin, J. Org. Chem. 2022, 42, 2070–2078.(侯金松, 杨高升*, “三(邻二甲胺基苄基)钇催化脂肪胺对烯腈的插入串联反应”, 有机化学, 2022, 42, 2070–2078.)

31. Jinsong Hou, Gaosheng Yang* and Zhuo Chai, “Lanthanide-Catalyzed Tandem Addition of Amines to Cyanoalkenes: Synthesis of Cyclic Amidines”, J. Org. Chem. 2022, 87, 453–463.

30. Peiying Su, Huimin Li, Wenlong Chen, Gen Luo, Gaosheng Yang* and Zhuo Chai, “Lewis Acid Catalyzed [3+2] Annulations of γ-Butyrolactam-Fused Donor–Acceptor Cyclopropanes with Aromatic Aldehydes and Aldimines”, Eur. J. Org. Chem. 2020, 5380–5387.

29. Xingyu Zhang, Manli Feng, Gaosheng Yang* and Zhuo Chai, “Sc(OTf)3-Catalyzed Chemodivergent Annulations of γ-Butyrolactone-Fused Cyclopropanes with Anthranils”, J. Org. Chem. 2020, 85, 430–440.

28. Yue Shen, Jun Chai, Gaosheng Yang*, Wenlong Chen and Zhuo Chai, “Stereocontrolled Synthesis of trans/cis-2,3-Disubstituted Cyclopropane 1,1-Diesters and Applications in the Syntheses of Furanolignans”, J. Org. Chem. 2018, 83, 12549–12558.

27. Pengfei Yang, Yue Shen, Manli Feng, Gaosheng Yang* and Zhuo Chai, “Lewis Acid Catalyzed [3+2] Annulation of γ-Butyrolactone Fused Cyclopropane with Aldehydes/Ketones”, Eur. J. Org. Chem. 2018, 4103–4112. 

26. Yue Shen, Pengfei Yang, Gaosheng Yang*, Wenlong Chen, Zhuo Chai, “Lewis acid-catalyzed enantiospecific [3 + 2] annulations of γ-butyrolactone fused cyclopropanes with aromatic aldehydes: synthesis of chiral furanolignans”, Org. Biomol. Chem. 2018, 16, 2688–2696.

25. Manli Feng, Pengfei Yang, Gaosheng Yang*, Wenlong Chen, Zhuo Chai, “FeCl3-Promoted [3 + 2] Annulations of γ-Butyrolactone Fused Cyclopropanes with Heterocumulenes”, J. Org. Chem. 2018, 83, 174–184.

24. Zhuo Chai, Yemei Wang, Mujun Tang, Xiaolong Mu, Jinsong Hou, Gaosheng Yang*, “Chiral rare-earth metal complexes with a tridentate amido-fluorenyl ligand: Syntheses, structures and catalytic performance”, J. Organomet. Chem. 2017, 846, 236–241.

23. Zhuo Chai, Jiang Chu, Yunyi Qi, Mujun Tang, Jinsong Hou and Gaosheng Yang*, “Half-sandwich chiral rare-earth metal complexes with linked tridentate amido-indenyl ligand: synthesis, characterization, and catalytic properties for intramolecular hydroamination”, RSC Adv. 2017, 7, 1759–1765.

22. Deju Hua, Pengfei Yang, Yue Shen, Gaosheng Yang*, Zhuo Chai*, “PCl5-mediated ring-openings of trans-2,3-disubstituted cyclopropane-1,1-diesters: A stereoselective way to trisubstituted vinyl chlorides”, Tetrahedron 2017, 73, 1205–1210.

21. Gaosheng Yang*, Tingting Wang, Jun Chai, and Zhuo Chai*, “AlCl3-Catalyzed [3+2] Annulations of cis-2,3-Disubstituted Cyclopropane 1,1-Diesters with Cyclic Ketones: Diastereoselective Construction of Spirotetrahydrofurans”, Eur. J. Org. Chem. 2015, 1040–1046.

20. Zhuo Chai, Dezhi Hua, Kui Li, Shuangliu Zhou, Jiang Chu, Gaosheng Yang*, “Rare-earth metal complexes with tridentate linked amido-indenyl ligand: Synthesis, characterization, and catalytic properties for intramolecular hydroamination”, J. Organomet. Chem. 2014, 768, 136–139.

19. Zhuo Chai, Dezhi Hua, Kui Li, Jiang Chu and Gaosheng Yang*, “A novel chiral yttrium complex with a tridentate linked amido-indenyl ligand for intramolecular hydroamination”, Chem. Commun. 2014, 50, 177–179.

18. Gaosheng Yang*, Yongxian Sun, Yue Shen, Zhuo Chai*, Shuangliu Zhou, Jiang Chu, and Jun Chai, “cis-2,3-Disubstituted Cyclopropane 1,1-Diesters in [3 + 2] Annulations with Aldehydes: Highly Diastereoselective Construction of Densely Substituted Tetrahydrofurans”, J. Org. Chem. 2013, 78, 5393–5400.

17. Yongxian Sun, Gaosheng Yang*, Zhuo Chai*, Xiaolong Mu and Jun Chai, “AlCl3-promoted [3 + 2] annulation of cis-2,3-disubstituted cyclopropane 1,1-diesters with isothiocyanates: stereoselective synthesis of densely substituted 2-iminodihydrothiophenes”, Org. Biomol. Chem. 2013, 11, 7859–7868.

16. Yongxian Sun, Gaosheng Yang*, Yue Shen, Zan Hua, Zhuo Chai*, “Stereoselective cyclopropanation of a-bromochalcone with diethyl malonate promoted by K2CO3”, Tetrahedron 2013, 69, 2733–2739.

15. Gaosheng Yang*, Chongrong Luo, Xiaolong Mu, Tingting Wang and Xin-Yuan Liu*, “Highly Efficient Enantioselective Three-Component Synthesis of 2-Amino-4H-Chromenes Catalysed by Chiral Tertiary Amine-Thioureas”, Chem. Commun. 2012, 48, 5880–5882.

14. Gaosheng Yang*, Yue Shen, Kui Li, Yongxian Sun, Yuanyuan Hua, “AlCl3-Promoted Highly Regio- and Diastereoselective [3+2]Cycloadditions of Activated Cyclopropanes and Aromatic Aldehydes: Construction of 2,5-Diaryl-3,3,4-trisubstituted Tetrahydrofurans”, J. Org. Chem. 2011, 76, 229–233. (This work has been highlighted in Synfacts)

13. 骆崇荣, 陈楠楠, 华德智, 杨高升*, 苯磺酰硫脲衍生物的无溶剂合成,有机化学, 2011, 31, 2167–2172.

12. Gaosheng Yang*, Yuanyuan Hua, Yue Shen, “K2CO3-Promoted Cascade Michael-Alkylation Reactions: A Facile Preparation of Diethyl trans-2,3-Disubstituted 1,1-Cyclopropanedicarboxylates”, Chin. J. Chem. 2009, 27, 1811–1819.

11. Xiaosheng Wang, Changwu Zheng, Shengli Zhao, Zhuo Chai, Gang Zhao*, Gaosheng Yang*, “Organocatalyzed Friedel–Craft-type reaction of 2-naphthol with β,γ-unsaturated a-keto ester to form novel optically active naphthopyran derivatives”, Tetrahedron: Asymmetry 2008, 19, 2699–2704.

10. Xiaosheng Wang, Gaosheng Yang*, and Gang Zhao*, “Enantioselective synthesis of naphthopyran derivatives catalyzed by bifunctional thiourea-tertiary   amines”, Tetrahedron: Asymmetry 2008, 19, 709–714.

  9. 吴红伟, 杨高升*, a-卤代酮与芳香二胺经氧化–缩合过程一锅法合成喹喔啉衍生物,有机化学, 2008, 28, 2132–2136.

  8. Gaosheng Yang, Huiwei Tang, Yizhi Li, Jing Hong, Zijian Guo, Longgen Zhu*, “Syntheses, structures, and properties of two dinuclear palladium (II) complexes of a single macrocyclic hexaaza ligand with two hydroxyethyl pendants”, Inorg. Chem. Commun. 2005, 8, 862–865.

  7. Gaosheng Yang, Ren Miao, Yizhi LI, Chen Jin, Jin Hong, Zijian Guo, Longgen Zhu*, “Self-inclusion of a New Calix[4]arene Derivative via Associated Acetonitrile: X-ray Diffraction and Density Functional Theory Studies”, Chin. J. Chem. 2005, 23, 852–856.

  6. Gaosheng Yang, Ren Miao, Yizhi Li, Jing Hong, Chuenmei Zhao, Zijian Guo and Longgen Zhu*, “Synergic effect of two metal centers in catalytic hydrolysis of methionine-containing peptides promoted by dinuclear palladium(II) hexaazacyclooctadecane complex”, Dalton Trans. 2005, 1613–1619.

  5. Gaosheng Yang, Ren Miao, Chen Jin, Yuhua Mei, Huiwei Tang, Jin Hong, Zijian Guo and Longgen Zhu*, “Determination of binding sites in carboplatin-bound cytochrome c using electrospray ionization mass spectrometry and tandem mass spectrometry”, J. Mass Spectrom. 2005, 40, 1005–1016.

  4. Gaosheng Yang, Chen Jin, Yizhi Li, Jing Hong, Ren Miao, Chuenmei Zhao, Zijian Guo and Longgen Zhu*, “Conformations and Structures of Two Novel Upper Rim Disubstituted Derivatives of Tetra-O-alkylcalix[4]arene: The Effect of Substituents”, J. Incl. Phenom. Macrocycl. Chem. 2005, 52, 119–127.

  3. Gaosheng Yang, Chen Jin, Jing Hong, Zijian Guo, Longgen Zhu*, “Ab initio and density functional theory studies on vibrational spectra of palladium (II) and platinum (II) complexes of methionine and histidine: effect of theoretical methods and basis sets”, Spectrochim. Acta Part A 2004, 60, 3187–3195.

  2. Gaosheng Yang, Jian-Bing Hu, Gang Zhao*, Yu Ding and Min-Hua Tang, “Catalytic enantioselective borane reduction of aromatic ketones with sulfonyl (S)-prolinol”, Tetrahedron: Asymmetry 1999, 10, 4307–4311.

  1. Gaosheng Yang, Xiao-juan Xie, Gang Zhao, Yu Ding*, “Palladium catalyzed cross-coupling reaction of organoboronic acids with β-(perfluoroalkyl)ethyl   iodides”, J. Fluorine Chem. 1999, 98, 159–161.

 会议论文

11. 祁云毅,王业梅,侯金松,冯曼丽,苏培盈,杨鹏飞,杨高升*, “含手性配位性侧链的单茂稀土金属有机化合物的合成、结构及催化性能”, 第十九届全国金属有机化学学术讨论会, 472, 中国, 杭州, 2016年10月28日–31日.

10. 王业梅,沈悦,杨鹏飞,杨高升*, “(1R,2R)-N,N-二甲基-N'-[2-(9-芴基)乙基]-1,2-环己二胺稀土配合物的合成及其催化性能研究”, 中国化学会第九届有机化学会议, 534, 中国, 长春, 2015年7月28日–31日.

  9. 王婷婷,柴俊,祁云毅,沐小龙,杨高升*, “AlCl3促进2,3-二取代-1,1-环丙烷二羧酸二乙酯与C=X键的 [3 + 2] 形式环加成反应研究”, 第十八届全国金属有机化学学术讨论会, 235, 中国, 兰州, 2014年8月19日–22日.

  8. 楚江,王业梅,唐慕君,华徳举,杨高升*, “手性半夹心稀土金属有机配合物的合成及其催化氨基烯烃分子内氢胺化/环化反应研究”, 第十八届全国金属有机化学学术讨论会, 236, 中国, 兰州, 2014年8月19日–22日.

  7. 陈楠楠, 王业梅, 唐幕君, 杨高升*, “二甲基硅基桥联双(N,N-二甲基乙二胺)稀土金属配合物的合成及其催化芳香醛、酮的氢磷化反应”, 中国化学会第八届有机化学会议, 4078, 中国, 重庆, 2013年10月17日–20日.

  6. 华德智, 李奎, 楚江, 杨高升*, “桥联茚基二胺稀土配合物的合成及其催化烯烃氢胺化反应”, 第十七届全国金属有机化学学术讨论会, P1-97, 中国, 北京, 2012年10月19日–22日.

  5. 李奎, 华德智, 楚江, 杨高升*, “桥联茚基手性二胺稀土配合物的合成及其催化烯烃氢胺化反应”, 第十七届全国金属有机化学学术讨论会, P1-98, 中国, 北京, 2012年10月19日–22日.

  4. 孙永先, 华赞, 杨高升*, “多取代D-A型环丙烷衍生物与碳硫双键的[3+2]环加成反应研究”, 第十届江淮有机化学论坛, 58, 中国, 合肥, 2012年11月2日–4日.

  3. 骆崇荣, 王婷婷, 孙永先, 杨高升*, “2-氨基-4H-色烯衍生物的不对称有机催化三组分合成”, 中国化学会第七届有机化学会议, 1-134, 中国, 南京, 2011年11月12日–15日. 

  2. 华德智, 骆崇荣, 李奎, 杨高升*, “手性叔胺–硫脲催化不对称三组分反应研究”, 中国化学会第七届有机化学会议, 1-135, 中国, 南京, 2011年11月12日–15日. 

  1. 沈悦, 吴红伟, 杨高升*, “DMSO作用下?-溴代苯乙酮与2,3-二氨基马来腈的反应研究”, 中国化学会第六届有机化学会议, P537(上册), 中国, 西安, 2009年8月17日–20日. 

 专利

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